Chemical insights into the larger sooting tendency of 2-methyl-2-butene compared to n-pentane
نویسندگان
چکیده
منابع مشابه
The uptake of methyl vinyl ketone, methacrolein, and 2-methyl-3-butene-2-ol onto sulfuric acid solutions.
To investigate the link between molecular structure, reactivity, and partitioning of oxygenated organic compounds in acidic aerosols, the uptake of three compounds found in the atmosphere, methyl vinyl ketone (MVK), methacrolein (MACR), and 2-methyl-3-butene-2-ol (MBO), by sulfuric acid solutions has been measured using a rotated wetted-wall reactor (RWW) coupled to a chemical ionization mass s...
متن کاملExperimental and Kinetic Modeling Study of 2-Methyl-2-Butene: Allylic Hydrocarbon Kinetics.
Two experimental studies have been carried out on the oxidation of 2-methyl-2-butene, one measuring ignition delay times behind reflected shock waves in a stainless steel shock tube, and the other measuring fuel, intermediate, and product species mole fractions in a jet-stirred reactor (JSR). The shock tube ignition experiments were carried out at three different pressures, approximately 1.7, 1...
متن کاملN-Methyl-2-thiocytisine
The rings of the three-ring cytisine system in the title compound [systematic name: (1R,5S)-1,2,3,4,5,6-hexa-hydro-1,5-methano-8H-pyrido[1,2-a][1,5]diazo-cine-8-thione], C(12)H(16)N(2)S, have planar [maximum deviation 0.0170 (7) Å], half-chair and chair conformations. In the crystal structure, relatively short and directional C-H⋯π inter-actions and weaker secondary C-H⋯S contacts join the mol-...
متن کامل2-Methyl-N-phenylbenzamide
In the structure of the title compound (NP2MBA), C(14)H(13)NO, the conformation of the C-O bond is syn to the ortho-methyl substituent in the benzoyl phenyl ring, while the N-H bond is anti to the ortho-methyl substituent. The structure of NP2MBA closely resembles that of 2-chloro-N-phenyl-benzamide, with similar bond parameters. The dihedral angle between the phenyl and benzoyl rings is 88.05 ...
متن کامل2-Methyl-N-(2-methylbenzoyl)benzenesulfonamide
In the title compound, C(15)H(15)NO(3)S, the 2-methyl-phenyl ring bonded to the sulfonyl group is disordered with site-occupation factors of 0.75:0.25. The dihedral angles between the two aromatic rings are 67.6 (1) and 69.2 (1)° for the major and the minor occupied sites, respectively. In the crystal, mol-ecules are linked into centrosymmetric dimers by pairs of N-H⋯O hydrogen bonds.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Combustion and Flame
سال: 2019
ISSN: 0010-2180
DOI: 10.1016/j.combustflame.2019.06.029